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Barcelona faced PSG at the Parc des Princes on Wednesday evening knowing they needed a miracle to make the quarter-finals.
The two sides met three weeks ago at Camp Nou, with Kylian Mbappe putting on a masterclass.
The French forward netted a brilliant hat-trick as PSG emerged 4-1 winners.
Barca started well in France, with Serginio Dest hitting the crossbar and Lionel Messi coming within inches of tapping home.
However, it was PSG who took the lead and in controversial circumstances.
A ball was swung in from the left and Mauro Icardi went down inside the box under contact from Clement Lenglet.
Nothing was given at the time but replays showed that the Frenchman had accidentally trod on his opponent's foot.
Despite Icardi having no chance of getting the ball, VAR was consulted and referee Anthony Taylor pointed to the spot.
Kylian Mbappe then made no mistake as he gave his side the lead.
Barcelona then restored parity on the evening and it came through the boot of their magician, Lionel Messi.
The Argentine scored one of the best goals of his career as his fierce strike from 30 yards found the top corner.
What. A. Goal. Absolutely majestic from Messi.
More to follow...